Organic Chemistry - Chemistry 3371

Fall, 2005


Professor Edward R. Biehl          Text: Organic 
Chemistry
Room 231D, Fondren Science Bldg     Wade, 6th Edition
Phone 768-1280                      Study Guide & Solns Manual, Simek     
ebiehl@smu.edu                      



	

		
Course Outline
			

				

					Week of
					Mon.
					Wed.
					Fri
				

				

					Aug. 15
					X
					X
					Ch.1
				

				

					Aug. 22
					Ch. 1
					Ch. 2
					Ch. 2
				

				

					Aug. 29
					Ch. 3
					Ch. 3
					Ch. 3
				

				

					Sept. 5
					Labor day
					Ch 3
					EXAM 1
				

				

					Sept. 12
					Ch. 4
					Ch. 4 
					Ch. 4
				

				

					Sept. 19
					Ch. 5
					Ch. 5
					Ch. 65
				

				

					Sept. 26
					Ch. 5
					Ch. 5
					EXAM II
				

				

					Oct. 03
					Ch. 6
					Ch. 6
					Ch. 6
				

				

					Oct. 10
					X
					Ch.6
					Ch. 7
				

				

					Oct. 17
					Ch. 7
					Ch. 8 
					Ch. 8
				

				

					Oct. 24
					Ch. 8
					Ch. 9
					EXAM III
				

				

					Oct. 31
					Ch.9
					Ch.10 
					Ch.10 
				

				

					Nov. 07
					Ch. 10
					Ch. 10
					Ch.11
				

				

					Nov. 14
					Ch. 11
					Ch. 12
					EXAM IV
				

				

					Nov. 21
					Ch. 12
					THANKSGIVING
					X 
				

				

					Nov. 28
					Ch. 12
					Review
					READING DAY 
				

			
* Last day to drop class with grade of WP 
**Last day to withdraw from University
 FINAL EXAM  Dec. 6, 2005 11:30AM - 2:30PM (room 131 FS)

		

	

	
PRACTICE EXAMS

	

		Chapter 1 ppt

	
Chapter 1

	

	

		

			

				
					
				
				

					ACID        
					pKA
					CONJ  BASE 
				

				

					    HI       
					-10
					I-
				

				

					    HBr     
					-9
					Br-
				

				

					    HCl     
					-7
					Cl-
				

				

					    HF       
					3.45
					F-
				

				

					    MeCO2H    
					4.75
					MeCO2-
				

				

					    H2CO3   
					6.37
					HCO3-
				

				

					    HCN       
					9.31
					CN-
				

				

					    NH4+     
					9.4
					NH3
				

				

					    PhOH     
					10
					PhO-
				

				

					    EtOH      
					17
					EtO-
				

				

					    CH3COCH3 
					20
					Ch3COCH2
				

				

					    NH3      
					33
					NH2-
				

				

					    CH4   
					48
					CH3-
				

			

		
Bonding and Molecular Properties

		
Chapter 2 ppt 
Chapter 2
	

	
 

	
Structure and Stereochemistry of Alkanes

	
Chapter 3 ppt.  	Chapter 3 pdf  
 
			
			

Key to Exam I  
 

	
Old Exam #1.pdf

	
 

	
The Study of Chemical Reactions - Wadeppt     Chapter 4.pdf           
   

	
 

	
Problem Ch. 4

	

		1c,2a,3a,b,8a,b,9,10,11,14,17a,b,18,19b-d,20,23,24,35,37,39d,e,42b,c,d,46b,c,e

	
 

	

Exam II Key to questions 13-17  
 

	
Chapter 5.ppt       
Stereochemistry: "Optical Isomerism"

	
 

	
Problems Ch. 5 

	
2e,3c,d,j,k,5b,f,g,6c,e,h,15b,16a,c,17e,18a,d,f,20a,b,d,f,21e, 22a,b, 26a,d,i,o, 28a,d, 30a,c,f,g, 35a, 37 (for the hearty, only)     

	
 

	
Chapter 6 Alkyl Halides: 
Nucelophilic Substitution and Elimination

	
 

	
Problems Chapter 6-- 2a,b,d,3g,j,k,11a,c,12b,14b,e,f, 16, 18, 19, 20b,c,e. 

	
21, 22, 24, 26a,c,d, 27, 29,31,33,35-3738,44-46,51-56, 60, 66,73 (for the brave).

	
 

	
Chapter 7 Alkenes:  Structure and Synthesis:  EZ, Elimination of Alkyl Halides
                      and Dehydration of Alcohols

	
Problems Chapter 7-- 4, 7, 8h,i, 11e - i, 13, 15, 17, 19, 22, 23,

	
31, 33, 34b, 38, 41, 43, 46, 53

	
Chapter 8. ppt Reaction of Alkenes: Electrophilic Addition, Hydroboration,
                      Carbene Addition, Halogenation, Epoxidation, Syn-Hydroxylation,
                      Oxidative Cleavage. 

	
Chapter 9 Chapter 9       
Structure and Synthesis of Alcohols

	
Chapt 9: 7c,e,8b,c,11a,12a,b,13a-d,16a,18,2,f,21a,c23d,e,27b,h,j,29d,e,32,a,c,d,g,I,l,m,34b,d,e,g,I,j,36b,e37c,d,g,j,38, 40
 

	
Chapter 10
Reaction of Alcohols: Oxidation, Ester Formation, Dehydration

	
Wade Ppt chapter 10

	
Problems Chapter 10  - 1a,c,2a,b,5a,c,7b,11g,h,12b,d,13a,c,14a,b,15a17a,18b,22a,e,23b,d,24a,26a,d,31e,f,35a,c,37a,ce,38a,c,d,i,j,39b,e,f,40b,e,41a,b,42a,e,

	
 

	
Wade Chapter 11

	
Problems Chapter 11 - 1,2,5a,b,16b,d,9,15,21a,e,22e,41d,k,n,42d,43a,48a,b,
 

	
Infrared Spectroscopy and Mass Spectrometry - next semester

	
 

	
Chapter 12
Nuclear Magnetic Spectrosocopy

	
 

	
Practice for Exam 4

	
Fall02_Exam4.pdf

	
Chem3371_exam4.pdf

	
 

	
Exam 4

		Exam 4

		
key to Exam 4
 

Homework

Students are expected to attempt all assigned problems

Grading

See Blackboard for grading information

Important Internet Numbers

Chemistry Department home page:http://www.smu.edu/~chemistry/